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ASTM D6667-04

ASTM D6667-04

Standard Test Method for Determination of Total Volatile Sulfur in Gaseous Hydrocarbons and Liquefied Petroleum Gases by Ultraviolet Fluorescence

2012-12-20 /Historical
Superseeded by:
Significance and Use:

The sulfur content of LPG, used for fuel purposes, contributes to SOx emissions and can lead to corrosion in engine and exhaust systems. Some process catalysts used in petroleum and chemical refining can be poisoned by sulfur bearing materials in the feed stocks. This test method can be used to determine sulfur in process feeds, to measure sulfur in finished products, and can also be used for compliance determinations when acceptable to a regulatory authority.


1.1 This test method covers the determination of total volatile sulfur in gaseous hydrocarbons and liquefied petroleum (LP) gases. It is applicable to analysis of natural, processed, and final product materials containing sulfur in the range of 1 to 100 mg/kg (Note 1).

Note 1—An estimate of pooled limit of quantification (PLOQ), information regarding sample stability and other general information derived from the inter-laboratory study on precision can be referenced in the ASTM research report.

1.2 This test method may not detect sulfur compounds that do not vaporize under the conditions of the test.

1.3 This test method is applicable for total volatile sulfur determination in LP gases containing less than 0.35 % (mass/mass) halogen(s).

1.4 The values stated in SI units are to be regarded as standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See 3.1 and Sections 6 and 7 for specific warning statements.

analysis; butane; fluorescence; gases; hydrocarbon; isobutane; LP; LPG; liquefied; petroleum; propane; sulfur; ultraviolet
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